Quantitative Raman spectroscopic study of the H2CH4 gaseous system
Fang, Jing1,2; Chou, I-Ming1; Chen, Ying1; Chou, I-Ming(Chinese Acad Sci, Inst Deep Sea Sci & Engn, CAS Key Lab Expt Study Deep Sea Extreme Condit, Sanya 572000, Hainan, Peoples R China)
2018-04-01
发表期刊JOURNAL OF RAMAN SPECTROSCOPY
卷号49期号:4页码:710-720
产权排序第1完成单位 ; 第2完成单位
摘要The Raman spectra of pure H-2 and CH4 gases and their 5 gaseous mixtures were collected at pressures from 1 to 40MPa at ambient temperature. They were systematically analyzed in order to establish methodology for quantitative determination of composition and pressure of H2CH4 bearing fluid inclusions. The peak positions of 4 vibrational bands of H-2 in pure H-2 gas decrease first and then increase after reaching their minima values at about 30MPa. The wavenumbers of ?(1) band of CH4 in pure CH4 gas decreases in wavenumber monotonically in the entire investigated pressure range. In H2CH4 gaseous mixtures, both the peak positions of H-2 and CH4 shift to lower wavenumbers with increasing pressure. The peak positions of ?(1) band of CH4 can be used to determine the pressure of pure CH4 and CH4-dominated fluids, where the peak position shifts are sufficiently large for precise pressure determination. The peak widths of H-2 and CH4 in pure H-2 and CH4 gases and H2CH4 gaseous mixtures broaden as pressure increases. The peak area ratios and the peak height ratios between CH4 and H-2 in H2CH4 binary mixtures are sensitive to composition (i.e., molar ratio between CH4 and H-2) but are almost independent of pressure. Thus, the peak area or peak height ratios can be used to determine the composition of H2CH4 fluids. On the other hand, the peak height ratios of Q(1)(1) to Q(1)(3) bands in pure H-2 gas or H-2-dominated gaseous mixtures are sensitive to pressure and insensitive to composition. Therefore, in H-2-dominated fluids, the relative peak heights of Q(1)(1) and Q(1)(3) of H-2 is a better alternative for pressure determination. Based on our established Raman quantitative analysis method, we determined the composition and internal pressure of a natural H2CH4-bearing melt inclusion in quartz from Jiajika granite.
文章类型Article
关键词H2ch4 Gas System Quantitative Analysis Raman Spectroscopy Silicate Melt Inclusion
WOS标题词Science & Technology ; Technology
DOI10.1002/jrs.5337
URL查看原文
收录类别SCI
语种英语
关键词[WOS]FLUID INCLUSIONS ; PRESSURE DETERMINATION ; GAS-MIXTURES ; HYDROGEN ; DENSITY ; METHANE ; CO2 ; CALIBRATION ; EQUATION ; SHIFTS
WOS类目Spectroscopy
WOS记录号WOS:000430468200010
引用统计
被引频次:1[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.idsse.ac.cn/handle/183446/5930
专题深海科学研究部_深海极端环境模拟研究实验室
通讯作者Chou, I-Ming; Chou, I-Ming(Chinese Acad Sci, Inst Deep Sea Sci & Engn, CAS Key Lab Expt Study Deep Sea Extreme Condit, Sanya 572000, Hainan, Peoples R China)
作者单位1.Chinese Acad Sci, Inst Deep Sea Sci & Engn, CAS Key Lab Expt Study Deep Sea Extreme Condit, Sanya 572000, Hainan, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100871, Peoples R China
第一作者单位中国科学院深海科学与工程研究所
通讯作者单位中国科学院深海科学与工程研究所
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Fang, Jing,Chou, I-Ming,Chen, Ying,et al. Quantitative Raman spectroscopic study of the H2CH4 gaseous system[J]. JOURNAL OF RAMAN SPECTROSCOPY,2018,49(4):710-720.
APA Fang, Jing,Chou, I-Ming,Chen, Ying,&Chou, I-Ming.(2018).Quantitative Raman spectroscopic study of the H2CH4 gaseous system.JOURNAL OF RAMAN SPECTROSCOPY,49(4),710-720.
MLA Fang, Jing,et al."Quantitative Raman spectroscopic study of the H2CH4 gaseous system".JOURNAL OF RAMAN SPECTROSCOPY 49.4(2018):710-720.
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