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Solubility and dissolution mechanism of 4-chlorotoluene in subcritical water investigated in a fused silica capillary reactor by in situ Raman spectroscopy
Bei, Ke1; Zhang, Chuanyong1; Wang, Junliang1; Li, Kai1; Lyu, Jinghui1; Zhao, Jia1; Chen, Jie1; Chou, I-Ming2; Pan, Zhiyan1
2016-10-15
Source PublicationFLUID PHASE EQUILIBRIA
Volume425Pages:93-97
AbstractThe solubility of 4-chlorotoluene in subcritical water was measured using an optically transparent fused silica capillary reactor (FSCR). The total dissolution temperature of 4-chlorotoluene in subcritical water was visually determined. The dissolution uniformity of 4-chlorotoluene in subcritical water was confirmed by Raman spectroscopy. The solubility of 4-chlorotoluene linearly increased with increasing temperature in the range 262.3-293.8 degrees C. The dissolution mechanism of 4-chlorotoluene in subcritical water is proposed based on the Raman spectra of 4-chlorotoluene and water during the dissolution process in the FSCR. (C) 2016 Elsevier B.V. All rights reserved.
SubtypeArticle
KeywordSubcritical Water 4-chlorotoluene Solubility Fused Silica Capillary Reactor Raman Spectroscopy
WOS HeadingsScience & Technology ; Physical Sciences ; Technology
DOI10.1016/j.fluid.2016.05.018
URL查看原文
Indexed BySCI
Language英语
WOS KeywordHOT-COMPRESSED WATER ; POLYCYCLIC AROMATIC-HYDROCARBONS ; SUPERCRITICAL WATER ; PHASE-EQUILIBRIA ; DEGREES-C ; 473 K ; TEMPERATURES ; OXIDATION ; SYSTEMS ; DEPOLYMERIZATION
WOS SubjectThermodynamics ; Chemistry, Physical ; Engineering, Chemical
WOS IDWOS:000382341700013
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Cited Times:6[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Version同行评议接收稿
Identifierhttp://ir.idsse.ac.cn/handle/183446/1539
Collection深海科学研究部_深海极端环境模拟研究实验室
Affiliation1.Zhejiang Univ Technol, Dept Environm Sci & Engn, Hangzhou 310032, Zhejiang, Peoples R China
2.Chinese Acad Sci, Sanya Inst Deep Sea Sci & Engn, Lab Expt Study Deep Sea Extreme Condit, Sanya 572000, Peoples R China
Recommended Citation
GB/T 7714
Bei, Ke,Zhang, Chuanyong,Wang, Junliang,et al. Solubility and dissolution mechanism of 4-chlorotoluene in subcritical water investigated in a fused silica capillary reactor by in situ Raman spectroscopy[J]. FLUID PHASE EQUILIBRIA,2016,425:93-97.
APA Bei, Ke.,Zhang, Chuanyong.,Wang, Junliang.,Li, Kai.,Lyu, Jinghui.,...&Pan, Zhiyan.(2016).Solubility and dissolution mechanism of 4-chlorotoluene in subcritical water investigated in a fused silica capillary reactor by in situ Raman spectroscopy.FLUID PHASE EQUILIBRIA,425,93-97.
MLA Bei, Ke,et al."Solubility and dissolution mechanism of 4-chlorotoluene in subcritical water investigated in a fused silica capillary reactor by in situ Raman spectroscopy".FLUID PHASE EQUILIBRIA 425(2016):93-97.
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